Saturday, 13 July 2013

Daniel Rutherford, a Scottish Physician, discovered nitrogen in 1772. But it was Lavoisier, who proved that nitrogen is an element and that it was not a supporter of combustion and respiration. He called it 'azote' meaning 'no life'. The name 'Nitrogen' was given to it by Jean Antoine Chaptal (1756 - 1832), in the year 1790.

Some Basic Features of Nitrogen:-





SymbolN
Atomic Number7
Electronic Configuration2,5
FormulaN2
Relative Atomic Mass14
Relative Molecular Mass28
Vapor Density14
Valency1, 2, 3, 4, 5

1. Position

Nitrogen is the first member of the group VA. Other members of this group are phosphorus (P), arsenic (As), antimony (Sb) and bismuth (Bi).

2. Electronic configuration

Members of this group have five electrons in their valence shell.

3. Valency

The members of group VA generally show trivalent character but nitrogen shows more than one valency ranging from +1 to +5.
Example:
Oxide
of Nitrogen
N2ONON2O3NO2N2O5
NameNitrous OxideNitric OxideNitrogen TrioxideNitrogen DioxideNitrogen Pentoxide
Valency+1+2+3+4+5

4. Metallic character

Nitrogen is a non-metal. The non-metallic character of the VA group decreases on going down the group:

5. Reactivity

Members of group VA form hydrides, halides and oxy-acids. For example:
Hydrides

Oxy-acids

 

Halides

 

6. Oxides


The oxides of VA group members are acidic in nature. The acidic nature of the oxides decreases as we move down the group.

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