Sunday, 14 July 2013


The elements placed in group 7 (VIIA) of the periodic table are called halogens or salt producers. All these elements form salts called halides, e.g. NaCl, NaI, KCl, KI etc. Halogen is an ancient Greek word meaning 'salt producer'. Halogens have seven electrons in their valence shell and so are monovalent.

ElementAtomic numberElectronic configurationValencyStateColour
Fluorine92, 7-1GasGreenish but more yellow
Chlorine172, 8, 7-1GasGreenish yellow
Bromine352, 8, 18, 7-1LiquidDark red liquid
Iodine532, 8, 18, 18, 7-1SolidDark purple
Astatine852, 8, 18, 32, 18, 7-1--
Remember
Bromine is the only Liquid non-metal. Iodine when heated undergoes sublimation.
1.Chlorine is placed second after fluorine in group VIIA.
2. Other members of this group are fluorine, bromine, iodine and astatine (the last member is radioactive).
3. Members of this group are called 'halogens' meaning salt producers.
4. Atoms of halogens have seven electrons in their valence shell, thus show -1 valency.
5. Halogens may be solid, liquid or gas.
HalogenFluorineChlorineBromineIodine
StateGasGasLiquidSolid
ColourYellowGreenish yellowReddish brownDeep purple
6. The color of halogens becomes darker as we move down the group from fluorine to iodine.
7. The reactivity of halogens decreases as we move down the group. Fluorine is the most reactive element of this group.
8. Halogen acids
All the members of the group VII A form binary haloacids.
Examples:
HF - Hydrofluoric acid
HCl - Hydrochloric acid
HBr - Hydrobromic acid
HI - Hydroiodic acid
9. Oxy-acids
All the members of the group VII A also form oxy-acids.
Examples:
HClO - Hypochloric acid
HClO2 - Chlorus acid
HClO3 - Chloric acid
HClO4 - Perchloric acid
10. All the members of the group VII A are strong oxidising agents since they have a strong tendency to accept one electron in order to attain an octet.

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